Application of electro-fenton process for the treatment of methylene blue

The electrochemical removal of an aqueous solution containing 0.25 mM of methylene blue (MB), one of the most important thiazine dye, has been investigated by electro-Fenton process using a graphite-felt cathode to electrogenerate in situ hydrogen peroxide and regenerate ferrous ions as catalyst. The effect of operating conditions such as applied current, catalyst concentration, and initial dye content on MB degradation has been studied. MB removal and mineralization were monitored during the electrolysis by UV\u2013Vis analysis and TOC measurements. The experimental results showed that MB was completely removed by the reaction with \u2022OH radicals generated from electrochemically assisted Fenton\u2019s reaction, and in any conditions the decay kinetic always follows a pseudo-first-order reaction. The faster MB oxidation rate was obtained applying a current of 300 mA, with 0.3 mM Fe2+at T=35 \ub0C. In these conditions, 0.25 mM MB was completely removed in 45 min and the initial TOC was removed in 90 min of electrolysis, meaning the almost complete mineralization of the organic content of the treated solution

A Comprehensive Approach to Improve Performance and Stability of State-of-the- Art Air Electrodes for Intermediate Temperature Reversible Cells: An Impedance Spectroscopy Analysis

Solid oxide fuel cells (SOFC) are devices for the transformation of chemical energy in electrical energy. SOFC appear very promising for their very high efficiency, in addition to the capability to work in reverse mode, which makes them suitable for integration in production units powered with renewables. Research efforts are currently addressed to find chemically and structurally stable materials, in order to improve performance stability during long-term operation. In this work, we examine different approaches for improving stability of two state-of-the-art perovskite materials, La0.6Sr0.4Co0.2Fe0.8O3-\uf064 (LSCF) and Ba0.5Sr0.5Co0.8Fe0.2O3-\uf064 (BSCF), very promising as air electrodes. Two different systems are considered: (i) LSCF and BSCF porous electrodes impregnated by a nano-sized La0.8Sr0.2MnO3-\uf064 layer and (ii) LSCF-BSCF composites with the two phases in different volume proportions. The study considers the results obtained by electrochemical impedance spectroscopy investigation, observing the polarisation resistance (Rp) of each system to evaluate performance in typical SOFC operating conditions. Furthermore, the behaviour of polarisation resistance under the effect of a net current load (cathodic) circulating for hundreds of hours is examined, as parameter to evaluate long-term performance stability

Classification of argentine maize landraces in heterotic groups

26-33The genetic diversity of maize (Zea mays L) is a valuable and strategic natural resource that plays a key role in the breeding progress. However, exploitation of genetic variability from landraces has not reached a significant level of utilization in breeding programs in Argentina yet. In order to establish their breeding potential, the best 15 out of a group of about 300 landraces from Argentina, were evaluated for various agronomic characters in testcrosses with five lines representing different heterotic groups. Testcrosses were evaluated in nine environments during two growing seasons. A factorial array of those landraces and tester lines was used. Differences for landraces, testers, and landrace x tester interactions were detected for ear diameter and length, ear attachment and plant height, and grain yield. Yield data were further analyzed following additive main effects (landrace and tester) and multiplicative interaction (landrace x tester) models. The first two principal components were significant and accounted for 67 percent of that interaction. The first axis was consistent with the Argentine flint vs. US dent (Mo17), and US dent (B73) vs. US dent (Mo17) heterotic patterns. The second axis exhibited a contrast between Argentine flint and US dent (B73 or B73 derived line) heterotic groups. The first two principal components of the landrace x tester interaction and mean performance of testcrosses were considered to identify eight landraces as parents of three composite populations

Evaluation of Externality Costs in Life-Cycle Optimization of Municipal Solid Waste Management Systems

The development of sustainable solid waste management (SWM) systems requires consideration of both economic and environmental impacts. Societal life-cycle costing (S-LCC) provides a quantitative framework to estimate both economic and environmental impacts, by including “budget costs” and “externality costs”. Budget costs include market goods and services (economic impact), whereas externality costs include effects outside the economic system (e.g., environmental impact). This study demonstrates the applicability of S-LCC to SWM life-cycle optimization through a case study based on an average suburban U.S. county of 500 000 people generating 320 000 Mg of waste annually. Estimated externality costs are based on emissions of CO₂, CH₄, N₂O, PM_2.5, PM₁₀, NO_<i>x</i>, SO₂, VOC, CO, NH₃, Hg, Pb, Cd, Cr (VI), Ni, As, and dioxins. The results indicate that incorporating S-LCC into optimized SWM strategy development encourages the use of a mixed waste material recovery facility with residues going to incineration, and separated organics to anaerobic digestion. Results are sensitive to waste composition, energy mix and recycling rates. Most of the externality costs stem from SO₂, NO_<i>x</i>, PM_2.5, CH₄, fossil CO₂, and NH₃ emissions. S-LCC proved to be a valuable tool for policy analysis, but additional data on key externality costs such as organic compounds emissions to water would improve future analyses

Expectancies regarding the interaction between smoking and substance use in alcohol-dependent smokers in early recovery.

The purpose of this study was to investigate expectancies regarding the interaction between cigarette smoking and use of alcohol among alcohol-dependent smokers in early recovery, using the Nicotine and Other Substances Interaction Expectancies Questionnaire (NOSIE). Participants were 162 veterans, 97% male, with a mean age of 50 years, enrolled in a clinical trial aimed at determining the efficacy of an intensive smoking cessation intervention versus usual care. At baseline, participants were assessed on measures of smoking behavior, abstinence thoughts about alcohol and tobacco use, symptoms of depression, and smoking-substance use interaction expectancies. In addition, biologically verified abstinence from tobacco and alcohol was assessed at 26 weeks. Participants reported that they expected smoking to have less of an impact on substance use than substance use has on smoking (p &lt; .001). Severity of depressive symptoms was significantly associated with the expectancy that smoking provides a way of coping with the urge to use other substances (p &lt; .01). The expectation that smoking increases substance urges/use was predictive of prospectively measured and biologically verified abstinence from smoking at 26 weeks (p &lt; .03). The results add to our knowledge of smoking-substance use interaction expectancies among alcohol-dependent smokers in early recovery and will inform the development of more effective counseling interventions for concurrent alcohol and tobacco use disorders

El género Gomphocarpus (Apocynaceae: Asclepiadoideae) en la Argentina

Se reporta la presencia de dos especies del género Gomphocarpus (Apocynaceae, Asclepiadoideae) que crecen espontáneamente en la Argentina: G. fruticosus (escapada de cultivo) y G. physocarpus (naturalizada). Las mismas se describen, se indica su distribución geográfica, usos, polinización y dispersión. Además, se analiza el estatus de naturalización de estas especies en el país

Allocating the Burdens of Climate Action: Consumption-Based Carbon Accounting and the Polluter-Pays Principle

Action must be taken to combat climate change. Yet, how the costs of climate action should be allocated among states remains a question. One popular answer—the polluter-pays principle (PPP)—stipulates that those responsible for causing the problem should pay to address it. While intuitively plausible, the PPP has been subjected to withering criticism in recent years. It is timely, following the Paris Agreement, to develop a new version: one that does not focus on historical production-based emissions but rather allocates climate burdens in proportion to each state’s annual consumption-based emissions. This change in carbon accounting results in a fairer and more environmentally effective principle for distributing climate duties

The risk stratification of adverse neonatal outcomes in women with gestational diabetes (STRONG) study

Aims: To assess the risk of adverse neonatal outcomes in women with gestational diabetes (GDM) by identifying subgroups of women at higher risk to recognize the characteristics most associated with an excess of risk. Methods: Observational, retrospective, multicenter study involving consecutive women with GDM. To identify distinct and homogeneous subgroups of women at a higher risk, the RECursive Partitioning and AMalgamation (RECPAM) method was used. Overall, 2736 pregnancies complicated by GDM were analyzed. The main outcome measure was the occurrence of adverse neonatal outcomes in pregnancies complicated by GDM. Results: Among study participants (median age 36.8 years, pre-gestational BMI 24.8 kg/m2), six miscarriages, one neonatal death, but no maternal death was recorded. The occurrence of the cumulative adverse outcome (OR 2.48, 95% CI 1.59–3.87), large for gestational age (OR 3.99, 95% CI 2.40–6.63), fetal malformation (OR 2.66, 95% CI 1.00–7.18), and respiratory distress (OR 4.33, 95% CI 1.33–14.12) was associated with previous macrosomia. Large for gestational age was also associated with obesity (OR 1.46, 95% CI 1.00–2.15). Small for gestational age was associated with first trimester glucose levels (OR 1.96, 95% CI 1.04–3.69). Neonatal hypoglycemia was associated with overweight (OR 1.52, 95% CI 1.02–2.27) and obesity (OR 1.62, 95% CI 1.04–2.51). The RECPAM analysis identified high-risk subgroups mainly characterized by high pre-pregnancy BMI (OR 1.68, 95% CI 1.21–2.33 for obese; OR 1.38 95% CI 1.03–1.87 for overweight). Conclusions: A deep investigation on the factors associated with adverse neonatal outcomes requires a risk stratification. In particular, great attention must be paid to the prevention and treatment of obesity

Sustainable Pavement Management. Integrating Economic, Technical, and Environmental Aspects in Decision Making

Sustainability, which is founded in the reconciliation of economic, environmental and social aspects, has become a major issue for infrastructure managers. The economic and environmental impacts of pavement maintenance are not negligible. More than 400 billion USD are invested globally each year in pavement construction and maintenance. These tasks increase the environmental impacts of vehicle operation by 10%. Because maintenance should be technically appropriate, it is important to integrate technical, economic and environmental aspects in the evaluation of maintenance alternatives over the life cycle of pavement. However, these aspects are normally assessed in different units that are difficult to combine in the decision-making process. This research examines and compares different methods for the integrated consideration of technical, economic and environmental aspects. This study aims to assist highway agencies, researchers and practitioners with the integration of these aspects for the sustainable management of pavement. For this purpose, a set of maintenance alternatives for asphalt pavements are evaluated. Different methods for the integration of these aspects are explored, leading to recommendations for the most suitable methods for different scenarios. Because of this analysis, the Analytic Hierarchy Process (AHP) is recommended when the number of alternatives is reduced. In these situations, the AHP leads to results that are similar to those of the Weighting Sum and Multi-Attribute approaches that are frequently used for intuitive selection. However, when the number of alternatives is large, pair comparison becomes difficult when using the AHP and the Weighting Sum method becomes more appropriate.The authors gratefully acknowledge the scholarship awarded by the Vicerrectoria de Investigacion from the Pontificia Universidad Catolica de Chile and funded by the Ministerio de Educacion de Chile. The research team acknowledges FONDEF-Comision Nacional de Investigacion Cientifica y Technologica (CONICYT) 2009 for funding the project Research and Development of Solutions for Urban Pavement Management in Chile. In addition, the authors sincerely appreciate the funding provided by CONICYT and the National Research Center for Integrated Natural Disaster Management.Torres Machí, C.; Chamorro, A.; Pellicer Armiñana, E.; Yepes, V.; Videla, C. (2015). Sustainable Pavement Management. Integrating Economic, Technical, and Environmental Aspects in Decision Making. Transportation Research Record. 2523:56-63. doi:10.3141/2523-07S56632523Chester, M. V., & Horvath, A. (2009). Environmental assessment of passenger transportation should include infrastructure and supply chains. Environmental Research Letters, 4(2), 024008. doi:10.1088/1748-9326/4/2/024008Chamorro, A., & Tighe, S. L. (2009). Development of a Management Framework for Rural Roads in Developing Countries. Transportation Research Record: Journal of the Transportation Research Board, 2093(1), 99-107. doi:10.3141/2093-12Torres-Machi, C., Chamorro, A., Yepes, V., & Pellicer, E. (2014). Current models and practices of economic and environmental evaluation for sustainable network-level pavement management. Revista de la construcción, 13(2), 49-56. doi:10.4067/s0718-915x2014000200006Haas, R., Tighe, S. L., & Falls, L. C. (2006). Determining Return on Long-Life Pavement Investments. Transportation Research Record: Journal of the Transportation Research Board, 1974(1), 10-17. doi:10.1177/0361198106197400102Wu, Z., Flintsch, G., Ferreira, A., & Picado-Santos, L. de. (2012). Framework for Multiobjective Optimization of Physical Highway Assets Investments. Journal of Transportation Engineering, 138(12), 1411-1421. doi:10.1061/(asce)te.1943-5436.0000458Wu, Z., & Flintsch, G. W. (2009). Pavement Preservation Optimization Considering Multiple Objectives and Budget Variability. Journal of Transportation Engineering, 135(5), 305-315. doi:10.1061/(asce)te.1943-5436.0000006Cafiso, S., Di Graziano, A., Kerali, H. R., & Odoki, J. B. (2002). Multicriteria Analysis Method for Pavement Maintenance Management. Transportation Research Record: Journal of the Transportation Research Board, 1816(1), 73-84. doi:10.3141/1816-09Giustozzi, F., Crispino, M., & Flintsch, G. (2012). Multi-attribute life cycle assessment of preventive maintenance treatments on road pavements for achieving environmental sustainability. The International Journal of Life Cycle Assessment, 17(4), 409-419. doi:10.1007/s11367-011-0375-6Nathman, R., McNeil, S., & Van Dam, T. J. (2009). Integrating Environmental Perspectives into Pavement Management. Transportation Research Record: Journal of the Transportation Research Board, 2093(1), 40-49. doi:10.3141/2093-05Robinette, C., & Epps, J. (2010). Energy, Emissions, Material Conservation, and Prices Associated with Construction, Rehabilitation, and Material Alternatives for Flexible Pavement. Transportation Research Record: Journal of the Transportation Research Board, 2179(1), 10-22. doi:10.3141/2179-02Osorio, A., Chamorro, A., Tighe, S., & Videla, C. (2014). Calibration and Validation of Condition Indicator for Managing Urban Pavement Networks. Transportation Research Record: Journal of the Transportation Research Board, 2455(1), 28-36. doi:10.3141/2455-04Saaty, T. L. (1990). How to make a decision: The analytic hierarchy process. European Journal of Operational Research, 48(1), 9-26. doi:10.1016/0377-2217(90)90057-